brass-hardware

Topic: Nickel Chrome Plating on Aluminum Castins

On nickel chorme plating an aluminum die cast product, we are getting blisters on the surface of the product. This blistering does not occur immediately after removing the product from the chrome bath, but it happens a few hours after the pating process. We have seen that the blistering occurs only after chrome plating and does not happen if we remove the piec from the nickel bath ( bright bath ) What is it that we are doing wrong.

DustinGebhardt

Re: Nickel Chrome Plating on Aluminum Castins

Can you please describe your entire process to us?  I have a feeling that your first coating is not adhereing to the surface of the aluminum and allowing the chrome solution to get underneath and attack the substrate. 


First, I would recommend that you check your pretreatment steps.  A good cleaner is required to remove any dirt and oils.  A good etch will give you greatly better adhesion once removed with a good de-smut/de-ox in the nest step.  It could be that you are not in the de-ox long enough, or that the bath is not strong enough to remove the etch-oxide very well.

You didn't state what kind of strike you are using (Watts nickel, sulfamate nickel, alkaline cyanide/non-cyanide copper?).  I hope that you are using one.



Also, rinsing is key in aluminum processes.  A single stage rinse between steps will often lead to failure.  2- or 3-stage rinsing  is required.  And the rinses must be clean.  Especially with casting, which can be porous, you can trap solution in the pores and this can easily lead to failure.

Are the blisters small or large?  Are they over the entire surface or only in certain areas?

-Dustin Gebhardt,
CEF
Plating Engineer
Danaher Tool Group
Gastonia, NC

brass-hardware

Re: Nickel Chrome Plating on Aluminum Castins

Thank you for your response. We have been electroplating products made in brass, and this is our first time electroplating a product made in Aluminum. Our process is as under- Buffing & Polishing on bench polishers - degreasing in an ultrasonic machine using trichloroethylene - soak cleaning in zictane 73  ( for 1 minute )- single water rinse - dip in Alzincate D ( for 1/2 a minute ) - single water rinse - bright nickel bath ( 20 minutes ) - nickel drag out - double water rinse - chrome bath ( for 2 minutes ) - chrome drag out - double water rinse - hot water rinse.

I am quite certain that we have not followed a proper procedure, and would request you to suggest the proper procedure and chemicals to be used.

Thanks Yogesh Modi.

brass-hardware

Re: Nickel Chrome Plating on Aluminum Castins

Thank you for your response. We have been electroplating products made in brass, and this is our first time electroplating a product made in Aluminum. Our process is as under- Buffing & Polishing on bench polishers - degreasing in an ultrasonic machine using trichloroethylene - soak cleaning in zictane 73  ( for 1 minute )- single water rinse - dip in Alzincate D ( for 1/2 a minute ) - single water rinse - bright nickel bath ( 20 minutes ) - nickel drag out - double water rinse - chrome bath ( for 2 minutes ) - chrome drag out - double water rinse - hot water rinse.

I am quite certain that we have not followed a proper procedure, and would request you to suggest the proper procedure and chemicals to be used.

Thanks Yogesh Modi.

DustinGebhardt

Re: Nickel Chrome Plating on Aluminum Castins

A typical plating-on-aluminum process will look similar to this:

Soak, 5-10 minutes or as needed

Rinse (multiple rinses)

Etch, 30sec to 3 minutes

Rinse, multiple

De-oxidize, 30sec to 3 minutes

Rinse, multiple

Zincate, 1-3 minutes

Rinse, multiple

Zincate strip, 30-90 sec

Rinse, multiple

Zincate, 2-4 minutes

Rinse, multiple

Strike bath (nickel sulfamate, Watts nickel, cyanide or alakline non-cyanide copper, etc)

Rinse, multiple

Bright copper, 30minutes to 3 hours (optional)

Rinse, multiple

At this point, many people remove the part from the process and buff/polish the part again, in order to achieve the brightest finish.  After the copper cycle, the part can go through your normal nickel/chrome, just like it was brass.



Also, the double zincate step is optional. A single zincate works for many places.  My experience has been in the aluminum wheel industry, and wheels are subject to very harsh conditions.  Without the double zincate, the wheels would fail much quicker.  Some places also do a double etch/de-ox cycle, to ensure a very clean part.


You can contact your local chemical vendor to get the correct chemicals.


-Dustin Gebhardt,
CEF
Plating Engineer
Danaher Tool Group
Gastonia, NC

brass-hardware

Re: Nickel Chrome Plating on Aluminum Castins

Hello Dustin. Thanks for your response.