Temperatures in an e-polish bath can drastically affect the work being produced. Depending upon the bath and base metal, high/low temps could cause uneven polishing, preferential dissolving of corner (rounding of sharp edges), pitting (especially true of alloys and aluminum), or a reduction in polishing rate among other things. And the manufacturing process for the part also plays a role, as forgings act differently than casting, which are different from stampings.
In many manufacturing processes, the edges of the piece are under more internal stress than elsewhere on the part. This makes them more susceptible to attack by the e-polish. Normally, the e-polish chemical is designed to take that into account and it tries not to attack those areas by using inhibitors and other things. However, when you change the temp, you change the way the different parts of the bath work together and their respective rates of reaction. Now, corners may get attacked faster, which would round them off.
Machined castings and alloys are also notorious for having a microscopic non-homogenous structure. Under a mid to high power microscope, the structure of the alloy becomes apparent as you can differentiate one metal from the other. In castings, often the surface of the part is slightly different than the internal areas, and you expose the internal areas when you machine the casting. Again, changing the temps can cause the e-polish chemical to preferentially go after one part of the alloy, which could cause pitting and other defects.
Stay within the vendors range and you should be okay. And make sure you know what material you are dealing with. One person's aluminum may be night and day different from the next guys. I've seen a few e-polish job shops that struggle with this on a daily basis.
-Dustin Gebhardt,
CEF
Plating Engineer
Danaher Tool Group
Gastonia, NC